- Title
- Photocatalytic behavior of phthalocyanine-silver nanoparticle conjugates supported on polystyrene fibers
- Creator
- Khozile, Phindile, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2014
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/189909
- Identifier
- vital:44946
- Identifier
- xlink:href="https://doi.org/10.1016/j.molcata.2014.07.031"
- Description
- Herein, carbazole derivatized non-peripheral (1,(4)-tetra(carbazol-2-yloxy)phthalocyaninatozinc(II), 3-TCbZnPc) and peripheral (2,(3)-tetra(carbazol-2-yloxy)phthalocyaninato zinc(II), 4-TCbZnPc) are conjugated to silver nanoparticles and their photochemical and photophysical behavior are reported. The presence of silver nanoparticles resulted in reduced fluorescence, and increased triplet and singlet oxygen quantum yields. The conjugates were further electrospun into polystyrene fibers, and employed for the photodegradation of methyl orange. The photodegradation of methyl orange using all functionalized fibers followed first order kinetics, and was faster when the conjugates with silver nanoparticles were used. The non-peripherally substituted 3-TCbZnPc gave better photocatalytic activity compared to its peripherally substituted counterpart (4-TCbZnPc). The hybrid electrospun fibers provide great potential as active photocatalysts for degrading organic pollutants.
- Format
- computer, online resource, application/pdf, 1 online resource (8 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Journal of Molecular Catalysis A: Chemical, Khoza, P. and Nyokong, T., 2014. Photocatalytic behavior of phthalocyanine-silver nanoparticle conjugates supported on polystyrene fibers. Journal of Molecular Catalysis A: Chemical, 395, pp.34-41, Journal of Molecular Catalysis A: Chemical volume 395 p. 34 2014 1873-314X
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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- Visitors: 455
- Downloads: 52
Collections
Nyokong, Tebello (Distinguished Professor)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
RU Department of Chemistry
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